By Henry Taube
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Extra resources for Electron Transfer Reactions of Complex Ions in Solution
When primary bonds are affected in the course of the reaction, as is the case when an innersphere mechanism operates, it can be expected that, for some systems at least, the effects will persist long enough so that they can be observed in the products. The success of the demonstration [24, 25] that electron transfer between metal ions can take place 36 I I . ACTIVATED COMPLEXES FOR ELECTRON TRANSFER by an inner-sphere mechanism depended on choosing a system in which the opportunity mentioned could easily be exploited.
Phys. Chem. 56, 801-910 (1952). 46 I I . ACTIVATED COMPLEXES FOR ELECTRON TRANSFER 3. Comment by H. C. Brown following the paper by J. Silverman and R. W. Dodson, in which the influences of anions on rates of electron transfer were discussed, / . Phys. Chem. 56, 896 (1952). 4. W. F. Libby, / . Phys. Chem. 56, 863 (1952), and subsequent discussion. 5. A. M. Zwickel and H. Taube, / . Am. Chem. Soc. 83, 793 (1961). 6. R. B. Jordan, A. M. Sargeson, and H. Taube, Inorg. Chem. 5, 1091 (1966). 7. E. S.
81, 1288 (1959). 28. R. K. Murmann, F. A. Posey, and H. Taube, / . Am. Chem. Soc. 79, 262 (1957). 29. W. Kruse and H. Taube, 82, 526 (1960). 30. H. R. Hunt and H. Taube, / . Phys. Chem. 63, 124 (1959). 31. M. Green, K. Schug, and H. Taube, Inorg. Chem. 4, 1184 (1965). 32. A. E. Ogard and H. Taube, / . Am. Chem. Soc. 80, 1083 (1958). 33. 4 has been quoted, based on unpublished work of D. Bearcroft and H. Taube. The equilibrium isotope effect for this reaction has been remeasured [R. C. Splinter, J.