By Stanley M. Roberts, Ivan V. Kozhevnikov, Eric Derouane(eds.)
The chemist has an unlimited diversity of high-tech catalysts to take advantage of while operating in fine chemical synthesis however the catalysts are regularly challenging to take advantage of and require either time, ability and adventure to deal with competently. The Catalysts for advantageous Chemical Synthesis series contains validated and demonstrated strategies which provide a different diversity assets for chemists who paintings in natural chemistry.
"... of serious price to man made natural chemists..." (The Chemists, summer season 2003)
quantity three within the sequence specializes in catalysts for carbon-carbon bond formation and offers useful and detailed protocols on tips to use refined catalysts through the "inventors" and "developers" who created them. The combination of protocols and evaluate commentaries is helping the reader to simply and quickly understand and use the recent high-tech catalysts.Content:
Chapter 1 concerns of commercial high-quality Chemical Synthesis (pages 1–12): Mark W. Hooper
Chapter 2 Alkylation and Allylation adjoining to a Carbonyl staff (pages 13–33): Fumitoshi Kakiuchi, Satoshi Ueno, Naoto Chatani, Michael North, Jose A. Fuentes, Barry Lygo and Benjamin I. Andrews
Chapter three uneven Alkylation or Amination of Allylic Esters (pages 35–57): Maria Zablocka, Marek Koprowski, Jean?Pierre Majoral, Mathieu Achard, Gerard Buono, Jerome Bayardon, Denis Sinou, Matthias Lotz, Gernot Kramer, Katja Tappe, Paul Knochel, Pierluigi Barbaro, Claudio Bianchini, Giuliano Giambastiani and Antonio Togni
Chapter four Suzuki Coupling Reactions (pages 59–90): Ana S. Abreu, Paula M. T. Ferreira, Maria?Joao R. P. Queiroz, Jie Wu, Lisha Wang, Reza Fathi, Zhen Yang, Ramon E. Huertas, John A. Soderquist, Tatsuo Ishiyama, Norio Miyaura, Bin Tao, David W. Boykin, Colin Baillie, Lijin Xu, Jianliang Xiao, Matthew L. Clarke, J. Derek Woollins, Nicholas Marion, Oscar Navarro, Roy A. Kelly and Steven P. Nolan
Chapter five Heck Coupling Reactions (pages 91–112): Peter Nilsson, Mats Larhed, Lijin Xu, Jun Mo, Jianliang Xiao, Tim G. Kilroy, Yvonne M. Malone and Patrick J. Guiry
Chapter 6 Sonogashira Coupling Reactions (pages 113–125): Anupama Datta, Herbert Plenio, Chih?An Lin and Fen?Tair Luo
Chapter 7 Cross?Coupling Reactions (pages 127–153): Jun Terao, Nobuaki Kambe, Luis A. Sarandeses, Jose Perez Sestelo, Bryan A. Frieman, Bruce H. Lipshutz, John Mancuso, Masahiro Yoshida and Mark Lautens
Chapter eight Regioselective or uneven 1,2?Addition to Aldehydes (pages 155–168): Kui?Thong Tan, Shu?Sin Chng, Hin?Soon Cheng, Teck?Peng Loh, Jens Rudolph, Carsten Bolm, Marco Lombardo, Sebastiano Licciulli, Stefano Morganti and Claudio Trombini
Chapter nine Olefin Metathesis Reactions (pages 169–180): Syuzanna Harutyunyan, Anna Michrowska, Karol Grela, Stephen J. Connon, Aideen M. Dunne, Siegfried Blechert, G. Bhaskar and B. Venkateswara Rao
Chapter 10 Cyclisation Reactions (pages 181–200): Jaime Blanco?Urgoiti, Gema Dominguez, Javier Perez?Castells, Ligang Zhao, Xiyan Lu, Minsheng He, Aiwen Lei, Xumu Zhang, Hiroshi Shinokubo, Koichiro Oshima, Antonio Rosales, Juan M. Cuerva and Enrique Oltra
Chapter eleven uneven Aldol and Michael Reactions (pages 201–223): Masakatsu Shibasaki, Shigeki Matsunaga, Naoya Kumagai, Zhuo Tang, Liu?Zhu Gong, Ai?Qiao Mi, Yao?Zhong Jiang, Masahito Watanabe, Kunihiko Murata and Takao Ikariya
Chapter 12 Stereoselective Hydroformylation, Carbonylation and Carboxylation Reactions (pages 225–250): Bernhard Breit, Martin Wills, Simon W. Breeden, Stefania Cserepi?Szucs, Jozsef Bakos, C. Ramesh, Y. Kubota, Y. Sugi, Tomoko Matsuda, Tadao Harada, Toru Nagasawa and Kaoru Nakamura
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Extra info for Catalysts for Fine Chemical Synthesis: Metal Catalysed Carbon-Carbon Bond-Forming Reactions, Volume 3
Plaquevent, J. C. and Cahard, D. Tetrahedron: Asymmetry 2003, 14, 1671; Park, H. , Jeong, B. , Yoo, M. , Lee, J. , Park, B. , Kim, M. G. and Jew, S. S. Tetrahedron Lett. , Allbutt, B. and James, S. R. Tetrahedron Lett. 2003, 44, 5629. 2 MARIA ZABLOCKA, MAREK KOPROWSKI, JEAN-PIERRE MAJORAL, MATHIEU ACHARD and GE´RARD BUONO . . . . . . . . . . . . . . . . . . . . . . . 1 Synthesis of (2,6-dimethyl-phenyl)-(1-phenyl-2,3,3a,8a-tetrahydro-1H1-phospha-cyclopenta[a]inden-8-ylidene)-amines 1Rp .
The benzene solution is passed through a neutral alumina column (packing: Merck aluminum oxide 90 active, neutral activity I; 30 mm inner diameter Â 120 mm length; eluent: benzene (ca 400–600 mL)). The elution of RuH2(CO) (PPh3)3 is monitored by UV254. The benzene eluent is concentrated to ca 100 mL by rotary evaporation. To the concentrated solution is added 150 mL of methanol. At this point a white solid is precipitated. The resulting liquid is concentrated to ca 50 mL by rotary evaporation. The concentrated liquid is cooled in an ice bath to enforce precipitation of the solids.
3 Synthesis of 3-(1H,10 H,2H,20 H,3H,30 H-perfluorooctyl)-1-iodopropane . . 4 Synthesis of (9H,90 H,10H,100 H,11H,110 H,13H,130 H,14H,140 H,15H,150 Hperfluorotricosane-12,120 -diyl)-bis-[(4S)-4-phenyl-2-oxazoline] . . . . 5 Synthesis of (E)-Methyl 2-carbomethoxy-3,5-diphenylpent-4-enoate . . 6 Conclusion . . . . . . . . . . . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . FACILE SYNTHESIS OF NEW AXIALLY CHIRAL DIPHOSPHINE COMPLEXES FOR ASYMMETRIC .